Platinum-group elements (PGE) and rhenium in marine sediments across the Cretaceous-Tertiary boundary: constraints on Re-PGE transport in the marine environment     

Cin-Ty Aeolus Lee  Gerald J. Wasserburg 《Geochimica et cosmochimica acta》2003,67(4):655-670

The nature of Re-platinum-group element (PGE; Pt, Pd, Ir, Os, Ru) transport in the marine environment was investigated by means of marine sediments at and across the Cretaceous-Tertiary boundary (KTB) at two hemipelagic sites in Europe and two pelagic sites in the North and South Pacific. A traverse across the KTB in the South Pacific pelagic clay core found elevated levels of Re, Pt, Ir, Os, and Ru, each of which is approximately symmetrically distributed over a distance of ∼1.8 m across the KTB. The Re-PGE abundance patterns are fractionated from chondritic relative abundances: Ru, Pt, Pd, and Re contents are slightly subchondritic relative to Ir, and Os is depleted by ∼95% relative to chondritic Ir proportions. A similar depletion in Os (∼90%) was found in a sample of the pelagic KTB in the North Pacific, but it is enriched in Ru, Pt, Pd, and Re relative to Ir. The two hemipelagic KTB clays have near-chondritic abundance patterns. The ∼1.8-m-wide Re-PGE peak in the pelagic South Pacific section cannot be reconciled with the fallout of a single impactor, indicating that postdepositional redistribution has occurred. The elemental profiles appear to fit diffusion profiles, although bioturbation could have also played a role. If diffusion had occurred over ∼65 Ma, the effective diffusivities are ∼10⁻¹³ cm²/s, much smaller than that of soluble cations in pore waters (∼10⁻⁶ cm²/s). The coupling of Re and the PGEs during redistribution indicates that postdepositional processes did not significantly fractionate their relative abundances. If redistribution was caused by diffusion, then the effective diffusivities are the same. Fractionation of Os from Ir during the KTB interval must therefore have occurred during aqueous transport in the marine environment. Distinctly subchondritic Os/Ir ratios throughout the Cenozoic in the South Pacific core further suggest that fractionation of Os from Ir in the marine environment is a general process throughout geologic time because most of the inputs of Os and Ir into the ocean have Os/Ir ratios ≥1. Mass balance calculations show that Os and Re burial fluxes in pelagic sediments account for only a small fraction of the riverine Os (<10%) and Re (<0.1%) inputs into the oceans. In contrast, burial of Ir in pelagic sediments is similar to the riverine Ir input, indicating that pelagic sediments are a much larger repository for Ir than for Os and Re. If all of the missing Os and Re is assumed to reside in anoxic sediments in oceanic margins, the calculated burial fluxes in anoxic sediments are similar to observed burial fluxes. However, putting all of the missing Os and Re into estuarine sediments would require high concentrations to balance the riverine input and would also fail to explain the depletion of Os at pelagic KTB sites, where at most ∼25% of the K-T impactor’s Os could have passed through estuaries. If Os is preferentially sequestered in anoxic marine environments, it follows that the Os/Ir ratio of pelagic sediments should be sensitive to changes in the rates of anoxic sediment deposition. There is thus a clear fractionation of Os and Re from Ir in precipitation out of sea water in pelagic sections. Accordingly, it is inferred here that Re and Os are removed from sea water in anoxic marine depositional regimes.  相似文献   

Preservation of organic matter in mound-forming coral skeletons     

Anitra E Ingalls  Cindy Lee 《Geochimica et cosmochimica acta》2003,67(15):2827-2841

This study demonstrates that intracrystalline organic matter in coral skeletons is well preserved over century timescales. The extent of preservation of organic matter in coral skeletons was investigated by measuring total organic carbon (TOC), total hydrolyzable amino acid (THAA), chloropigment, and lipid concentrations in 0-300 year old annual growth bands from Montastraea annularis (Florida Keys) and Porites lutea (Red Sea). Organic matter intrinsic to the calcium carbonate mineral (intracrystalline) was analyzed separately from total skeletal organic matter. The Red Sea coral had less TOC (0.02-0.04 wt%) than the Florida Keys coral (0.04-0.11 wt%), but a higher percent of intracrystalline organic matter in all annual bands measured. Carbon in the form of THAA, most likely from mineral-precipitating proteins, contributed 30-45% of the TOC in both corals. Carbon in lipids represented about 3% of the TOC in the coral skeletons. Chlorophyll-a and b were present in annual bands where endolithic algae were present, but these compounds were minor contributors to TOC. The distribution of specific organic compounds showed that organic matter was well preserved throughout the time period sampled in both the total and intracrystalline pools. Variations in THAA were not correlated with TOC over time, suggesting that organic matter that is involved in biomineralization, like amino acids, may be deposited in response to different environmental factors than are other components of skeletal organic matter. Differences in the quantity and composition of organic matter between the two corals investigated here were assessed using principal components analysis and suggest that location, species and skeletal structure may all influence organic matter content and possibly the degree of physical protection of organic matter by the coral skeleton. Further, our study suggests that intracrystalline organic matter may be better protected from diagenesis than non-intracrystalline organic matter and may therefore be a more reliable source of organic matter for paleoceanographic studies than total skeletal organic matter.  相似文献   

Geospatial habitat change analysis in Pacific Northwest coastal estuaries   总被引：1，自引：0，他引：1  

Amy B. Borde  Ronald M. Thom  Steven Rumrill  Lee M. Miller 《Estuaries and Coasts》2003,26(4):1104-1116

  相似文献   

Fetch and Footprint of Turbulent Fluxes over Vegetative Stands with Elevated Sources   总被引：1，自引：0，他引：1  

Xuhui Lee 《Boundary-Layer Meteorology》2003,107(3):561-579

In this study, Raupach's localized near-field (LNF)theory is combined with appropriate parameterizations ofthe turbulence inside a canopy to investigate how airstability and source configuration influence the fluxfootprint and flux adjustment with fetch in theroughness sublayer. The model equations are solvednumerically. The flux footprint from the LNF predictionis in general more contracted than the prediction basedon the inertial sublayer similarity functions. Invery unstable conditions, the near-field effect causes thefootprint of the elevated canopy source to locatefurther upwind than that of the ground-level source, andthe combined footprint can become negative in situationswhere the two sources are of opposite sign. The fluxfootprint and flux adjustment with fetch in theroughness sublayer are sensitive to source configurationand the parameters specifying wind speed and theLagrangian time scale inside the canopy.  相似文献   

斜底面上的表面波理论          下载免费PDF全文

李国麟  黄伟健  杨纲凯  曾庆存  张铭 《大气科学》1997,21(6):649-658

考察了任意倾斜底面上的Kelvin波问题，并用线性化的控制方程分别研究了相应于垂直刚壁的和无限倾斜底面上的表面波频散关系。文中还对任意斜坡上的浅水表面波做了尺度分析，并把决定其频散关系的特征值问题简化为该斜坡上气压扰动的常微分方程，且用数值方法进行了求解。  相似文献   

Observation of gravity waves in a boreal forest     

X. Lee  H.H. Neumann  G. Hartog  R.E. Mickle  J.D. Fuentes  T.A. Black  P.C. Yang  P.D. Blanken 《Boundary-Layer Meteorology》1997,84(3):383-398

In this paper we report the results of the analysis of two 60-min wave events that occurred in a boreal aspen forest during the 1994 BOREAS (Boreal Ecosystems-Atmosphere Study) field experiment. High frequency wind and temperature data were provided by three 3-D sonic anemometer/thermometers and fourteen fine-wire thermocouples positioned within and above the forest. Wave phase speeds, estimated from information revealed by spectral analysis and linear plane wave equations, are 2.2 and 1.3 m s^-1 for the two events. The wavelengths are 130 m and 65 m respectively and are much larger than the vertical wave displacements. There is strong evidence from the present analysis and from the literature supporting our postulate that these waves are generated by shear instability. We propose that wind shear near the top of the stand is often large enough to reduce the gradient Richardson number below the critical value of 0.25 and thus is able to trigger the instability. When external conditions are favorable, the instability will grow into waves.  相似文献   

Constraints of Housing Age and Migration on Residential Mobility     

Dowell Myers  S. Simon Choi  Seong Woo Lee 《The Professional geographer》1997,49(1):14-28

This paper investigates the role of housing age in constraining residential mobility, measured as the percent of households that have moved into their homes in the past 15 months. The leading explanation for why mobility rates differ so much among regions of the United States has been the overall level of growth. The present analysis shows that the growth effect operates through both the newness of population (migration) and the newness of housing available for occupancy by all local residents. The posited explanation for this housing age effect is that progressively older units contain increasingly settled occupants, yielding fewer opportunities for in-movers in areas with older housing. It is empirically demonstrated that households in older housing have lower likelihood of recent mobility even after controlling for age, tenure, migration status, and state location of residence. The analysis reveals the temporal interdependency of mobility, migration, person age, and housing age.  相似文献   

Application of an optimum design technique for determining the coefficient of consolidation by using piezocone test data   总被引：4，自引：0，他引：4  

Y.S. Kim  S.R. Lee  Y.T. Kim 《Computers and Geotechnics》1997,21(4):885-293

For normally consolidated clay, several researchers have developed a number of theoretical time factors to determine the coefficient of consolidation from piezocone test results. However, depending on assumptions and analytical techniques, it could vary considerably, even for a specific degree of consolidation. In this paper a method is proposed to determine a consistent coefficient of consolidation by applying the concept of an optimum design technique over all ranges of the degree of consolidation. Initial excess pore pressure distribution is assumed to be capable of being obtained by the successive spherical cavity expansion theory. The dissipation of pore pressure is simulated by means of a two-dimensional linear-uncoupled axi-symmetric consolidation analysis. The minimization of differences between measured and predicted excess pore pressure was carried out by the BFGS unconstrained optimum design algorithm with a one-dimensional golden section search technique. By analyzing numerical examples and in-situ test results, it was found that the adopted optimum design technique gives consistent and convergent results.  相似文献   

任意圆弧形凸起地形中隧洞对入射平面SH波的影响   总被引：10，自引：2，他引：10       下载免费PDF全文

梁建文  罗昊  Vincent W.Lee 《地震学报》2004,26(5):495-508

借助辅助函数的思想， 采用波函数展开法给出了圆弧形凸起地形中隧洞对入射平面SH波影响问题的一个解析解．数值结果表明，凸起地形中隧洞的存在以及隧洞大小，对凸起地形表面运动，以及凸起地形中的隧洞的动应力集中均具有显著影响．   相似文献   

Evaluation of soil liquefaction in the Chi-Chi, Taiwan earthquake using CPT   总被引：1，自引：0，他引：1  

Chih-Sheng Ku  Der-Her Lee  Jian-Hong Wu 《Soil Dynamics and Earthquake Engineering》2004,24(9-10):659

During the 1999 Chi-Chi, Taiwan earthquake, many sand boiling phenomena were observed in central Taiwan, which caused severe ground settlement and structure damages. According to the installed accelerograms, the peak ground surface horizontal accelerations in the liquefaction-affected areas range from 774.42 to 121.3 gal. The writers carried out an extensive investigation of soil liquefaction in this earthquake. In this paper, we present results of the CPT exploration and post-earthquake liquefaction analysis. Two hundred and seventy five (275) cone penetration test data were collected from the liquefaction-affected areas, and 46 liquefaction case histories and 88 non-liquefaction case histories were derived that can be used to evaluate the accuracy of existing liquefaction evaluation models. In addition, the strength of the liquefied soils after earthquake and the implication of its liquefaction potential in the future event are discussed.  相似文献